Material Safety Information

Here is the Safety Data Sheet (SDS) pertaining to all Karribi paint by number kits.

 

Safety data sheet

According to 1907/2006/EC, Article 31

SECTION 1: Identification of the substance/mixture and of the company/undertaking

  • 1 Product Identifier: Karribi Paint by Numbers Kit for Adults and Children - Spring Birds Series
  • Product Line:
    • Karribi Paint by Numbers Kit for Adults and Children - Spring Birds Series (Bird I)
    • Karribi Paint by Numbers Kit for Adults and Children - Spring Birds Series (Bird II)
    • Karribi Paint by Numbers Kit for Adults and Children - Spring Birds Series (Bird III)
    • Karribi Paint by Numbers Kit for Adults and Children - Spring Birds Series (Bird IV)
    • Karribi Paint by Numbers Kit for Adults and Children - Spring Birds Series (Bird V)
    • Karribi Paint by Numbers Kit for Adults and Children - Spring Birds Series (Bird VI)
    • Karribi Paint by Numbers Kit for Adults and Children - Spring Birds Series (Bird VII)
    • Karribi Paint by Numbers Kit for Adults and Children - Spring Birds Series (Bird VIII)
    • Karribi Paint by Numbers Kit for Adults and Children - Spring Birds Series (Bird IX)
    • Karribi Paint by Numbers Kit for Adults and Children - Spring Birds Series (Bird X)
    • Karribi Paint by Numbers Kit for Adults and Children - Spring Birds Series (Bird XI)
    • Karribi Paint by Numbers Kit for Adults and Children - Spring Birds Series (Bird XII)
  • Material: Acrylic paint
  • 2 Relevant identified uses of the substance or mixture and uses advised against
  • Application of the substance/the mixture painting
  • 3 Details of the supplier of the safety data sheet
  • Manufacturer/supplier:

Company: Karribi Arts and Crafts

Address: 32222 Bruckners Way, Black Diamond, WA

ZIP code: 98010

Tel.: +1(425)765-8918

Email: info@karribi.com

  • 4 Emergency telephone number: +1(425)765-8918

SECTION 2: Hazards Identification

  • 1 Classification of the substance or mixture

 Classification according to regulation (EC) No 1272/2008

  GHS07

 Skin Sens. 1 H317 May cause an allergic skin reaction.

  • 2 Label Elements
  • Labelling according to Regulation (EC) No 1272/2008

 The product is classified and labelled according to the CLP regulation.

  • Hazard pictograms

  GHS07

  • Signal word Warning
  • Hazard-determining components of labeling:

 1,2-benzisothiazol-3(2H)-one

  • Hazard statements

 H317 May cause an allergic skin reaction.

  • Precautionary statements

P101          If medical advice is needed, have product container or label at hand.

P102          Keep out of reach of children.

P103          Read label before use.

P261          Avoid breathing dust/Fume/gas/mist/vapors/spray.

P280          Wear protective gloves.

P302+P352 IF ON SKIN: Wash with plenty of water.

P321          Specific treatment (see on this label).

P333+P313 If skin irritation or rash occurs: get medical advice/attention.

P501          Dispose of contents/container in accordance with local/regional/national/international regulations.

  • 3 Other hazards
  • Results of PBT and vPvB assessment
  • PBT: Not applicable.
  • vPvB: Not applicable.

 

SECTION 3: Composition/information on ingredients

  • 2 Mixtures
  • Description: Mixture of substances listed below with non-hazardous additions.

Dangerous components:

CAS: 9003-01-4

EC number: 618-347-7

2-Propenoic acid, homopolymer

substance with a Community workplace exposure limit

55.0%

CAS: 471-34-1

EINECS: 207-439-9

Calcium carbonate

substance with a Community workplace exposure limit

8.0%

CAS: 2634-33-5

EINECS: 220-120-9

Index number: 613-088-00-6

1,2-benzisothiazol-3(2H)-one

Eye Dam. 1, H318; Aquatic Acute 1, H400; Acute Tox. 4, H302; Skin Irrit. 2, H315; Skin Sens. 1, H317

0.3%

 

Non-dangerous components:

CAS: 13463-67-7

EINECS: 236-675-5

Titanium dioxide

30.0%

CAS: 7732-18-5

EINECS: 231-791-2

Water, distilled, conductivity or of similar purity

6.7%

  • Additional information: for the wording of the listed hazard phrases refer to section 16.

SECTION 4: First aid measures

  • 1 Description of first aid measures
  • After inhalation:

Supply fresh air and to be sure call for a doctor.

In case of unconsciousness place patient stable in side position for transportation.

  • After skin contact: Immediately wash with water and soap and rinse thoroughly.
  • After eye contact: Rinse opened eye for several minutes under running water.
  • After swallowing: If symptoms persist consult doctor.
  • 2 Most important symptoms and effects, both acute and delayed No further relevant information available.
  • 3 Indication of any immediate medical attention and special treatment needed No further relevant information available.

SECTION 5: Firefighting measures

  • 1 Extinguishing media
  • Suitable extinguishing agents: Use fire extinguishing methods suitable to surrounding conditions.
  • 2 Special hazards arising from the substance or mixture No further relevant information available.
  • 3 Advice for firefighters
  • Protective equipment: No special measures required.

SECTION 6: Accidental release measures

  • 1 Personal precautions, protective equipment and emergency procedures: Not required.
  • 2 Environmental precautions: Do not allow to enter sewers/surface or groundwater.
  • 3 Methods and material for containment and cleaning up:

Absorb with liquid-binding material (Sand, diatomite, acid binders, universal binders, sawdust).

  • 4 Reference to other sections

See section 7 for information on safe handling.

See section 8 for information on personal protection equipment.

See section 13 for disposal information.

SECTION 7: Handling and storage

  • 1 Precautions for safe handling No special precautions are necessary if used correctly.
  • Information about fire and explosion protection: No special measures required.
  • 2 Conditions for safe storage, including any incompatibilities
  • Storage:
  • Requirements to be met by storerooms and receptacles: No special requirements.
  • Information about storage in one common storage facility: Not required.
  • Further information about storage conditions:
  • 3 Specific end use(s) No further relevant information available.

SECTION 8: Exposure controls/Personal protection

  • Additional information about design of technical facilities: no further data; see item 7.
  • Additional information: The lists valid during the making were used as basis.
  • 2 exposure controls
  • Personal protective equipment:
  • General protective and hygienic measures:

Immediately remove all soiled and contaminated clothing.

Wash hands before breaks and at the end of work.

  • Respiratory protection: Not required.
  • Protection of hands: Protective gloves.

The glove material must be impermeable and resistant to the product/the substance/the preparation.

Due to missing tests no recommendation to the glove material can be given for the product/the preparation/the chemical mixture.

Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation

  • Material of gloves

The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of glove material cannot be calculated in advance and has therefore to be checked prior to the application.

  • Penetration time of glove material

The exact break through time must be found out by the manufacturer of the protective gloves and must be observed.

  • Eye protection: Goggles recommended during refilling

SECTION 9: Physical and chemical properties

·        9.1 Information on basic physical and chemical properties

·        General information

·        Appearance:

 

 

 

 

           Form: 

Paste

           Color:

Titanium White

·        Odour:

Odourless

·        Odour Threshold:

Not determined

PH value:

Not determined.

·        Change in condition:

          Melting point/ Freezing point:

          Initial boiling point and boiling range:

 

Undetermined.

Undetermined.

·        Flash point:

Not determined.

·        Flammability (solid, gas):

Not applicable.

·        Ignition temperature:

 

          Decomposition temperature:

Not determined.

·        Auto-Ignition temperature:

Not determined.

·        Explosive properties:

Not determined.

·        Explosion limits:

           Lower:  

           Upper:

 

Not determined.

Not determined.

·        Vapour pressure:

Not determined.

·        Density:

·        Relative density

·        Vapour density

·        Evaporation rate

Not determined.

Not determined.

Not determined.

Not determined.

·        Solubility in /Miscibility with water:

Not determined.

·        Partition coefficient: n-octanol/water:

Not determined.

·        Viscosity:

           Dynamic:

           Kinematic:

·        9.2 other information 

 

Not determined.

Not determined.

No further relevant information available.

 

SECTION 10: Stability and reactivity

  • 1 Reactivity: No further relevant information available.
  • 2 Chemical Stability
  • Thermal decomposition/ conditions to be avoided: No decomposition if used according to specifications.
  • 3 Possibility of hazardous reactions: No dangerous reactions known.
  • 4 Conditions to avoid: No further relevant information available.
  • 5 Incompatible materials: No further relevant information available.
  • 6 Hazardous decomposition products: No dangerous decomposition products known.

SECTION 11:  Toxicological information

  • 1 Information on toxicological effects
  • Acute toxicity Based on available data the classification criteria are met.

·        LD/LC50 values relevant for classification:

471-34-1 calcium carbonate

Oral

LD50

6,450 mg/kg (rat)

  • Primary irritant effect:
  • Skin corrosion/irritation Based on available data, the classification criteria are not met.
  • Serious eye damage/irritation Based on available data, the classification criteria are not met.
  • Respiratory or skin sensitization

May cause an allergic skin reaction.

  • CMR effects (carcinogenicity, mutagenicity, and toxicity for reproduction)
  • Germ cell mutagenicity Based on available data, the classification criteria are not met.
  • Carcinogenicity Based on available data, the classification criteria are not met.
  • Reproductive toxicity Based on available data, the classification criteria are not met.
  • STOT-single exposure Based on available data, the classification criteria are not met.
  • STOT-repeated exposure Based on available data, the classification criteria are not met.
  • Aspiration hazard Based on available data, the classification criteria are not met.

SECTION 12: Ecological information

  • 1 Toxicity
  • Aquatic toxicity: No further relevant information available.
  • 2 Persistence and degradability No further relevant information available.
  • 3 Bio accumulative potential No further relevant information available.
  • 4 Mobility in soil No further relevant information available.
  • Additional ecological information:
  • General notes:

Water hazard class 1(German regulation) (Self-assessment):  slightly hazardous for water.

Do not allow undiluted product or large quantities of it go reach ground water, water course or sewage system.

  • 5 Results of PBT and vPvB assessment
  • PBT: Not applicable.
  • VPVB: Not applicable.
  • 6 Other adverse effects No further relevant information available.

SECTION 13: Disposal considerations

  • 1 Waste treatment methods
  • Recommendation: Must not be disposed together with household garbage. Do not allow product to reach sewage system.
  • Uncleaned packaging:
  • Recommendation: Disposal must be made according to official regulations.

SECTION 14: Transport information

 

·        14.1 UN-Number

·        ADR, ADN, IMDG, IATA

Void

 

·        14.2 UN proper shipping name

·        ADR, ADN, IMDG, IATA

Void

 

·        14.3 Transport hazard class(es)

·        ADR, ADN, IMDG, IATA

·        Class

Void

·        14.4 Packing group

·        ADR, IMDG, IATA    

Void

·        14.5 Environmental hazards:             

Not applicable

·        14.6 Special precautions for user     

Not applicable

·        14.7 Transport in bulk according to Annex II of Marpol and the IBC Code

Not applicable

14.8 UN "Model Regulation":    

Void

 

SECTION 15: Regulatory information

  • 1 Safety, health and environmental regulations/specific for the substance or mixture
  • Directive 2012/18/EU
  • Named dangerous substances - ANNEX I None of the ingredients is listed.
  • REGULATION (EC) No 1907/2006 ANNEX XVII Conditions of restriction: 3
  • 2 Chemical safety assessment: A chemical Safety Assessment has not been carried out.

SECTION 16: Other information

This information is based on our present knowledge.  However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship.

This safety data sheet (6617)243-1495-1 is prepared upon applicant HEBI CHINJOO ART MATERIALS TECHNOLOGY CO, LTD'S request.  However, no SDS ingredients was provided by the applicant.  And no further testing data provided.  Therefore, this document is compiled in accordance with what we obtained.

 

  • Relevant phrases

H302 Harmful if swallowed.

H315 Causes skin irritation.

H317 May cause an allergic skin reaction.

H318 Causes serious eye damage.

H400 Very toxic to aquatic life.

  • Abbreviations and acronyms:

ADR Accord européen sur le transport des merchandises dangeruses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road)

IMDG:  International Maritime Code for Dangerous Goods.

IATA:  International Air Transport Association

GHS:  Globally Harmonized System of Classification and Labelling of Chemicals

EINECS:  European Inventory of Existing Commercial Chemical Substances

CAS:  Chemical Abstracts Service (division of the American Chemical Society)

LC50:  Lethal concentration, 50 percent

LD50:  Lethal dose, 50 percent

PBT:  Persistent, Bio accumulative and Toxic

VPvB:  very Persistent and very Bio accumulative

Acute Tox. 4: Acute Toxicity – Category 4

Skin Irrt. 2:  Skin corrosion irritation – Category 2

Eye Dam 1:  Serious eye damage eye irritation – Category 1

Skin Sens 1:  Skin sensitization – Category 1

Aquatic Acute 1: Hazardous to the aquatic environment – acute aquatic hazard – Category 1